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Abstract The selection of low-radioactive construction materials is of the utmost importance for rare-event searches and thus critical to the XENONnT experiment. Results of an extensive radioassay program are reported, in which material samples have been screened with gamma-ray spectroscopy, mass spectrometry, and $$^{222}$$ 222 Rn emanation measurements. Furthermore, the cleanliness procedures applied to remove or mitigate surface contamination of detector materials are described. Screening results, used as inputs for a XENONnT Monte Carlo simulation, predict a reduction of materials background ( $$\sim $$ ∼ 17%) with respect to its predecessor XENON1T. Through radon emanation measurements, the expected $$^{222}$$ 222 Rn activity concentration in XENONnT is determined to be 4.2 ( $$^{+0.5}_{-0.7}$$ - 0.7 + 0.5 )  $$\upmu $$ μ Bq/kg, a factor three lower with respect to XENON1T. This radon concentration will be further suppressed by means of the novel radon distillation system. 

The selection of low-radioactive construction materials is of utmost importance for the success of low-energy rare event search experiments. Besides radioactive contaminants in the bulk, the emanation of radioactive radon atoms from material surfaces attains increasing relevance in the effort to further reduce the background of such experiments. In this work, we present the$$^{222}$$${}^{222}$Rn emanation measurements performed for the XENON1T dark matter experiment. Together with the bulk impurity screening campaign, the results enabled us to select the radio-purest construction materials, targeting a$$^{222}$$${}^{222}$Rn activity concentration of$$10\,\mathrm{\,}\upmu \mathrm{Bq}/\mathrm{kg}$$$10\mu \mathrm{Bq}/\mathrm{kg}$in$$3.2\,\mathrm{t}$$$3.2t$of xenon. The knowledge of the distribution of the$$^{222}$$${}^{222}$Rn sources allowed us to selectively eliminate problematic components in the course of the experiment. The predictions from the emanation measurements were compared to data of the$$^{222}$$${}^{222}$Rn activity concentration in XENON1T. The final$$^{222}$$${}^{222}$Rn activity concentration of$$(4.5\pm 0.1)\,\mathrm{\,}\upmu \mathrm{Bq}/\mathrm{kg}$$$(4.5\pm 0.1)\mu \mathrm{Bq}/\mathrm{kg}$in the target of XENON1T is the lowest ever achieved in a xenon dark matter experiment.